Synthesis and characterisation of p-block complexes of biquinoline at different ligand charge states



: Hurmalainen J, Mansikkamaki A, Morgan IS, Peuronen A, Tuononen HM

Publisher: ROYAL SOC CHEMISTRY

: 2017

: Dalton Transactions

: DALTON TRANSACTIONS

: DALTON T

: 46

: 5

: 1377

: 1381

: 5

: 1477-9226

DOI: https://doi.org/10.1039/c6dt04504arsc.li/dalton

: https://pubs.rsc.org/en/content/articlelanding/2017/dt/c6dt04504a/unauth#!divAbstract


The first examples of p-block coordination complexes of biquinoline, namely [(biq)BCl2]Cl and [(biq)BCl2](.), were synthesized and structurally characterized. The acquired data allowed the estimation of the ligand charge state based on its metrical parameters. The subsequent use of this protocol, augmented with theoretical calculations, revealed ambiguities in the published data for transition metal complexes of biquinoline.



Last updated on 2024-26-11 at 21:56