A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Synthesis and characterisation of p-block complexes of biquinoline at different ligand charge states
Tekijät: Hurmalainen J, Mansikkamaki A, Morgan IS, Peuronen A, Tuononen HM
Kustantaja: ROYAL SOC CHEMISTRY
Julkaisuvuosi: 2017
Journal: Dalton Transactions
Tietokannassa oleva lehden nimi: DALTON TRANSACTIONS
Lehden akronyymi: DALTON T
Vuosikerta: 46
Numero: 5
Aloitussivu: 1377
Lopetussivu: 1381
Sivujen määrä: 5
ISSN: 1477-9226
DOI: https://doi.org/10.1039/c6dt04504arsc.li/dalton
Verkko-osoite: https://pubs.rsc.org/en/content/articlelanding/2017/dt/c6dt04504a/unauth#!divAbstract
Tiivistelmä
The first examples of p-block coordination complexes of biquinoline, namely [(biq)BCl2]Cl and [(biq)BCl2](.), were synthesized and structurally characterized. The acquired data allowed the estimation of the ligand charge state based on its metrical parameters. The subsequent use of this protocol, augmented with theoretical calculations, revealed ambiguities in the published data for transition metal complexes of biquinoline.
The first examples of p-block coordination complexes of biquinoline, namely [(biq)BCl2]Cl and [(biq)BCl2](.), were synthesized and structurally characterized. The acquired data allowed the estimation of the ligand charge state based on its metrical parameters. The subsequent use of this protocol, augmented with theoretical calculations, revealed ambiguities in the published data for transition metal complexes of biquinoline.