A1 Refereed original research article in a scientific journal
Synthesis and characterisation of p-block complexes of biquinoline at different ligand charge states
Authors: Hurmalainen J, Mansikkamaki A, Morgan IS, Peuronen A, Tuononen HM
Publisher: ROYAL SOC CHEMISTRY
Publication year: 2017
Journal: Dalton Transactions
Journal name in source: DALTON TRANSACTIONS
Journal acronym: DALTON T
Volume: 46
Issue: 5
First page : 1377
Last page: 1381
Number of pages: 5
ISSN: 1477-9226
DOI: https://doi.org/10.1039/c6dt04504arsc.li/dalton(external)
Web address : https://pubs.rsc.org/en/content/articlelanding/2017/dt/c6dt04504a/unauth#!divAbstract(external)
Abstract
The first examples of p-block coordination complexes of biquinoline, namely [(biq)BCl2]Cl and [(biq)BCl2](.), were synthesized and structurally characterized. The acquired data allowed the estimation of the ligand charge state based on its metrical parameters. The subsequent use of this protocol, augmented with theoretical calculations, revealed ambiguities in the published data for transition metal complexes of biquinoline.
The first examples of p-block coordination complexes of biquinoline, namely [(biq)BCl2]Cl and [(biq)BCl2](.), were synthesized and structurally characterized. The acquired data allowed the estimation of the ligand charge state based on its metrical parameters. The subsequent use of this protocol, augmented with theoretical calculations, revealed ambiguities in the published data for transition metal complexes of biquinoline.
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