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Expanding sample volume for microscopical detection of nanoplastics




TekijätHiltunen, Arto; Huopalainen, Joona; Mäkilä, Ermei; Häkkilä, Sirkku; Damlin, Pia; Hänninen, Jari

KustantajaElsevier BV

Julkaisuvuosi2024

JournalMarine Environmental Research

Tietokannassa oleva lehden nimiMarine Environmental Research

Artikkelin numero106806

Vuosikerta202

ISSN0141-1136

eISSN1879-0291

DOIhttps://doi.org/10.1016/j.marenvres.2024.106806

Verkko-osoitehttps://doi.org/10.1016/j.marenvres.2024.106806

Rinnakkaistallenteen osoitehttps://research.utu.fi/converis/portal/detail/Publication/459062647


Tiivistelmä

The extent of nanoplastic pollution has raised severe environmental and health concerns. While the means for microplastic detection are abundant, improved tools for nanoplastic detection are called-for. State-of-the-art microscopic techniques can detect nanoplastics down to tens of nanometers, however, only from small sample sizes (typically ∼ 10 μl). In this work, we describe a method that enables sampling of 1 l of seawater by the means of correlative Raman- and SEM-techniques. This is achieved by adapting common microplastic sample purification protocols to suit the nanoplastic study. In addition, we decorate a membrane filter with SERS-property to amplify the Raman signals. Together, the purification method combined with the use of the SERS-activated-membrane-filter enables identification and imaging of individual nanoplastic particles from significantly larger sample sizes than before. In the nanoscale the average recovery rate is 5 %. These results aim to provide useful tools for researchers in the fight against plastic pollution.


Ladattava julkaisu

This is an electronic reprint of the original article.
This reprint may differ from the original in pagination and typographic detail. Please cite the original version.




Julkaisussa olevat rahoitustiedot
Sakari Alhopuro Foundation


Last updated on 2025-27-01 at 19:28