A1 Refereed original research article in a scientific journal

Expanding sample volume for microscopical detection of nanoplastics




AuthorsHiltunen, Arto; Huopalainen, Joona; Mäkilä, Ermei; Häkkilä, Sirkku; Damlin, Pia; Hänninen, Jari

PublisherElsevier BV

Publication year2024

JournalMarine Environmental Research

Journal name in sourceMarine Environmental Research

Article number106806

Volume202

ISSN0141-1136

eISSN1879-0291

DOIhttps://doi.org/10.1016/j.marenvres.2024.106806(external)

Web address https://doi.org/10.1016/j.marenvres.2024.106806(external)

Self-archived copy’s web addresshttps://research.utu.fi/converis/portal/detail/Publication/459062647(external)


Abstract

The extent of nanoplastic pollution has raised severe environmental and health concerns. While the means for microplastic detection are abundant, improved tools for nanoplastic detection are called-for. State-of-the-art microscopic techniques can detect nanoplastics down to tens of nanometers, however, only from small sample sizes (typically ∼ 10 μl). In this work, we describe a method that enables sampling of 1 l of seawater by the means of correlative Raman- and SEM-techniques. This is achieved by adapting common microplastic sample purification protocols to suit the nanoplastic study. In addition, we decorate a membrane filter with SERS-property to amplify the Raman signals. Together, the purification method combined with the use of the SERS-activated-membrane-filter enables identification and imaging of individual nanoplastic particles from significantly larger sample sizes than before. In the nanoscale the average recovery rate is 5 %. These results aim to provide useful tools for researchers in the fight against plastic pollution.


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Funding information in the publication
Sakari Alhopuro Foundation


Last updated on 2025-27-01 at 19:28