Synthesis, characterization, and reactivity toward Nickel(II) of the new saturated 14-Membered P2S2 macrocycles cis-and trans-1,8-diphenyl-1,8-diphospha-4,12-dithiacyclotetradecane - UTU Tutkimustietojärjestelmä

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Synthesis, characterization, and reactivity toward Nickel(II) of the new saturated 14-Membered P2S2 macrocycles cis-and trans-1,8-diphenyl-1,8-diphospha-4,12-dithiacyclotetradecane

Tekijät: José Antonio Muñoz, Lluis Escriche, Jaume Casabó, Consuelo Pérez-Jiménez, Raikko Kivekäs, Reijo Sillanpää

Kustantaja: American Chemical Society

Julkaisuvuosi: 2019

Journal: Inorganic Chemistry

Tietokannassa oleva lehden nimi: Inorganic Chemistry

Vuosikerta: 36

Numero: 5

Aloitussivu: 947

Lopetussivu: 949

Sivujen määrä: 4

ISSN: 0020-1669

eISSN: 1520-510X

DOI: https://doi.org/10.1021/ic960611l

Verkko-osoite: 10.1021/ic960611l

Tiivistelmä

The new saturated 14-membered P2S2 macrocycle 1,8-diphenyl-1,8-diphospha-4,12-dithiacyclotetradecane (14P2S2) has been synthesized and the cis- and trans-isomers have been isolated and characterized. The complexing behavior of these two isomers toward Ni(II) has been tested, and the crystal structure of the [Ni(trans-14P2S2)(CH3CN)](ClO4)2 complex has been solved.