Synthesis, characterization, and reactivity toward Nickel(II) of the new saturated 14-Membered P2S2 macrocycles cis-and trans-1,8-diphenyl-1,8-diphospha-4,12-dithiacyclotetradecane - UTU Research Portal

A1 Refereed original research article in a scientific journal

Synthesis, characterization, and reactivity toward Nickel(II) of the new saturated 14-Membered P2S2 macrocycles cis-and trans-1,8-diphenyl-1,8-diphospha-4,12-dithiacyclotetradecane

Authors: José Antonio Muñoz, Lluis Escriche, Jaume Casabó, Consuelo Pérez-Jiménez, Raikko Kivekäs, Reijo Sillanpää

Publisher: American Chemical Society

Publication year: 2019

Journal: Inorganic Chemistry

Journal name in source: Inorganic Chemistry

Volume: 36

Issue: 5

First page : 947

Last page: 949

Number of pages: 4

ISSN: 0020-1669

eISSN: 1520-510X

DOI: https://doi.org/10.1021/ic960611l

Web address : 10.1021/ic960611l

Abstract

The new saturated 14-membered P2S2 macrocycle 1,8-diphenyl-1,8-diphospha-4,12-dithiacyclotetradecane (14P2S2) has been synthesized and the cis- and trans-isomers have been isolated and characterized. The complexing behavior of these two isomers toward Ni(II) has been tested, and the crystal structure of the [Ni(trans-14P2S2)(CH3CN)](ClO4)2 complex has been solved.