A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Oxidovanadium(V) amine bisphenolates as epoxidation, sulfoxidation and catechol oxidation catalysts
Tekijät: Salonen Pasi, Peuronen Anssi, Lehtonen Ari
Kustantaja: Elsevier B.V.
Julkaisuvuosi: 2017
Journal: Inorganic Chemistry Communications
Lehden akronyymi: Inorg Chem Commun
Vuosikerta: 86
Aloitussivu: 165
Lopetussivu: 167
Sivujen määrä: 1
ISSN: 1387-7003
eISSN: 1879-0259
DOI: https://doi.org/10.1016/j.inoche.2017.10.017
Verkko-osoite: https://www.sciencedirect.com/science/article/pii/S1387700317306925
Rinnakkaistallenteen osoite: https://research.utu.fi/converis/portal/detail/Publication/27312788
Air-stable oxidovanadium(V) complexes with tetradentate amine bisphenolate ligands were made by the reaction of VOSO4·xH2O and ligand precursors in MeOH solutions. Isolated compounds were studied as catechol oxidase
models as well as catalysts for epoxidation and sulfoxidation
reactions. All compounds can catalyse such oxidation reactions without
notable structure-activity correlations. The 51V NMR studies indicate that the complexes turn to the number of different species during the catalytic experiments.
Ladattava julkaisu This is an electronic reprint of the original article. |  |
