A1 Refereed original research article in a scientific journal
Oxidovanadium(V) amine bisphenolates as epoxidation, sulfoxidation and catechol oxidation catalysts
Authors: Salonen Pasi, Peuronen Anssi, Lehtonen Ari
Publisher: Elsevier B.V.
Publication year: 2017
Journal: Inorganic Chemistry Communications
Journal acronym: Inorg Chem Commun
Volume: 86
First page : 165
Last page: 167
Number of pages: 1
ISSN: 1387-7003
eISSN: 1879-0259
DOI: https://doi.org/10.1016/j.inoche.2017.10.017
Web address : https://www.sciencedirect.com/science/article/pii/S1387700317306925
Self-archived copy’s web address: https://research.utu.fi/converis/portal/detail/Publication/27312788
Air-stable oxidovanadium(V) complexes with tetradentate amine bisphenolate ligands were made by the reaction of VOSO4·xH2O and ligand precursors in MeOH solutions. Isolated compounds were studied as catechol oxidase
models as well as catalysts for epoxidation and sulfoxidation
reactions. All compounds can catalyse such oxidation reactions without
notable structure-activity correlations. The 51V NMR studies indicate that the complexes turn to the number of different species during the catalytic experiments.
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