A chiral diamine bis-phenolate complex of dioxomolybdenum(VI)



: Manian RDRS, Leino R, Wichmann O, Lehtonen A

Publisher: ELSEVIER SCIENCE BV

: 2009

Inorganic Chemistry Communications

INORGANIC CHEMISTRY COMMUNICATIONS

: INORG CHEM COMMUN

: 12

: 10

: 1004

: 1006

: 3

: 1387-7003

DOI: https://doi.org/10.1016/j.inoche.2009.08.005


A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.



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