A1 Refereed original research article in a scientific journal
A chiral diamine bis-phenolate complex of dioxomolybdenum(VI)
Authors: Manian RDRS, Leino R, Wichmann O, Lehtonen A
Publisher: ELSEVIER SCIENCE BV
Publication year: 2009
Journal:: Inorganic Chemistry Communications
Journal name in source: INORGANIC CHEMISTRY COMMUNICATIONS
Journal acronym: INORG CHEM COMMUN
Volume: 12
Issue: 10
First page : 1004
Last page: 1006
Number of pages: 3
ISSN: 1387-7003
DOI: https://doi.org/10.1016/j.inoche.2009.08.005
Abstract
A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.
A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.
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