A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
A chiral diamine bis-phenolate complex of dioxomolybdenum(VI)
Tekijät: Manian RDRS, Leino R, Wichmann O, Lehtonen A
Kustantaja: ELSEVIER SCIENCE BV
Julkaisuvuosi: 2009
Lehti:: Inorganic Chemistry Communications
Tietokannassa oleva lehden nimi: INORGANIC CHEMISTRY COMMUNICATIONS
Lehden akronyymi: INORG CHEM COMMUN
Vuosikerta: 12
Numero: 10
Aloitussivu: 1004
Lopetussivu: 1006
Sivujen määrä: 3
ISSN: 1387-7003
DOI: https://doi.org/10.1016/j.inoche.2009.08.005
Tiivistelmä
A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.
A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.
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