A1 Refereed original research article in a scientific journal

UV-Sensing Cellulose Fibers Manufactured by Direct Incorporation of Photochromic Minerals




AuthorsFang Wenwen, Sairanen Emma, Vuori Sami, Rissanen Marja, Norrbo Isabella, Lastusaari Mika, Sixta Herbert

PublisherAmerican Chemical Society

Publication year2021

JournalACS Sustainable Chemistry and Engineering

Journal name in sourceACS Sustainable Chemistry and Engineering

Volume9

Issue48

First page 16338

Last page16346

eISSN2168-0485

DOIhttps://doi.org/10.1021/acssuschemeng.1c05938

Web address https://pubs.acs.org/doi/10.1021/acssuschemeng.1c05938

Self-archived copy’s web addresshttps://research.utu.fi/converis/portal/detail/Publication/68405382


Abstract

Textile-based wearable sensors integrated into daily wear offer opportunities for on-demand, real-time self-diagnosis to monitor health conditions with changing environmental surroundings and hazards. One still underrated environmental hazard is accumulated UV irradiation, causing skin burns, accelerated aging, and skin cancers. Here, we have demonstrated a sustainable fiber manufacture process to integrate photochromic hackmanite micro-particles directly into a cellulose body to achieve UV-sensing functionality in daily-life textiles. The hackmanite particles were dispersed into an ionic liquid cellulose dope using ultrasonication and nanofibrillated cellulose as a dispersant, resulting in good spinnability. The obtained fibers possess high mechanical strength with up to 10% photochromic hackmanite loading. To demonstrate its application in wearable UV sensors, the fibers were spun into yarn and then knitted into a piece of jersey fabric. The coloration of hackmanite-incorporated textiles under UV irradiation is readily quantified by image analysis using red–green–blue ratios, which was further utilized for UV dosimetry with a smartphone application showcasing the practical use of the UV sensor. The UV-sensing functionality remained the same after intensive washing and abrasion tests, further demonstrating the feasibility of its application in everyday garments.


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