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Molecularly imprinted fluoroprobes doped with Ag nanoparticles for highly selective detection of oxytetracycline in real samples




TekijätWang Jixiang, Zou Lihua, Xu Jingjing, Zhang Rong, Zhang Hongbo

KustantajaELSEVIER

Julkaisuvuosi2021

JournalAnalytica Chimica Acta

Tietokannassa oleva lehden nimiANALYTICA CHIMICA ACTA

Lehden akronyymiANAL CHIM ACTA

Artikkelin numeroARTN 338326

Vuosikerta1161

Sivujen määrä7

ISSN0003-2670

eISSN1873-4324

DOIhttps://doi.org/10.1016/j.aca.2021.338326

Rinnakkaistallenteen osoitehttps://research.utu.fi/converis/portal/detail/Publication/54383483


Tiivistelmä
A molecularly imprinted polymer (MIP), which is synthesized by a nanomolding process around a template, has emerged as a promising analytical tool for environmental quality monitoring and food safety test.In this work, a fluoroprobe with Ag-doped MIP nanolayer (16 nm thickness) is successfully prepared for the highly selective detection of oxytetracycline (OTC) in real samples (i.e. Yangtze River water, swine urine). In the MIP nanolayer, two functional monomers (i.e. 4-(2-acrylamidoethylcarbamoyl)-3-fluorophenylboronic acid, methacrylic acid) synergistically constitute the specific recognition sites. Meanwhile, the doped Ag enhances the detection sensitivity (with a detection limit of 5.38 nM) and accelerates the detection rate (within 2.5 min) even in real samples. Therefore, the present study paves the way for the preparation of MIP-based fluoroprobes, showing great prospects in environmental quality and food safety tests.(c) 2021 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).

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Last updated on 2024-26-11 at 21:36