A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Oxidation of glucose and arabinose mixtures over Au/Al2O3
Tekijät: Franz Sebastian, Shcherban Nataliya D., Simakova Irina L., Peurla Markus, Eränen Kari, Wärnå Johan, Salmi Tapio, Murzin Dmitry Yu.
Kustantaja: SPRINGER
Julkaisuvuosi: 2021
Journal: Reaction Kinetics, Mechanisms and Catalysis
Tietokannassa oleva lehden nimi: REACTION KINETICS MECHANISMS AND CATALYSIS
Lehden akronyymi: REACT KINET MECH CAT
Vuosikerta: 132
Aloitussivu: 59
Lopetussivu: 72
Sivujen määrä: 14
ISSN: 1878-5190
eISSN: 1878-5204
DOI: https://doi.org/10.1007/s11144-020-01901-w
Rinnakkaistallenteen osoite: https://research.utu.fi/converis/portal/detail/Publication/50964476
Oxidation of a mixture of glucose and arabinose over 1% Au deposited on alumina was investigated in a semi-batch reactor varying pH, temperature and partial pressure of oxygen. Elevation of the latter enhancing the rate induced also losses in selectivity to aldonic acids. A kinetic model representing the catalytic oxidation reactions of arabinose and glucose along with respective isomerization to fructose and ribulose was developed. Calculations based on the model were able to describe experimental data in a reliable way.
Ladattava julkaisu This is an electronic reprint of the original article. |  |
