A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Bioinspired Mo, W and V complexes bearing a highly hydroxyl- functionalized Schiff base ligand
Tekijät: Pasi Salonen, Anssi Peuronen, Ari Lehtonen
Kustantaja: ELSEVIER SCIENCE SA
Julkaisuvuosi: 2020
Journal: Inorganica Chimica Acta
Tietokannassa oleva lehden nimi: INORGANICA CHIMICA ACTA
Lehden akronyymi: INORG CHIM ACTA
Artikkelin numero: ARTN 119414
Vuosikerta: 503
Sivujen määrä: 14
ISSN: 0020-1693
eISSN: 1873-3255
DOI: https://doi.org/10.1016/j.ica.2020.119414
Rinnakkaistallenteen osoite: https://research.utu.fi/converis/portal/detail/Publication/46452041
A series of bioinspired dioxidomolybdenum(vi), dioxidotungsten(vi) and oxidovanadium(v) complexes [MoO2(H2LSaltris], [WO2(H2LSaltris] and [VO(HLSaltris)](2) were prepared by the reaction of a hydroxyl-rich Schiff base proligand N-(1,3-dihydroxy-2-(hydroxymethyl)propan 2 yl) 3,5 di-tert butylsalicylaldimine (H4LSaltrisc) with metal precursors in methanol solutions. Molybdenum and tungsten complexes crystallize as mononuclear molecules, whereas the vanadium complex forms dinuclear units. From the complexes, [VO(HLSaltris)](2) shows activity in the oxidation of 4-tert-butylcatechol and 3,5-di-tert-butylcatechol, mimicking the action of the dicopper enzyme catechol oxidase.
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