A1 Refereed original research article in a scientific journal

Synthesis of Organometallic Oligonucleotides through Oximation with Metalated Benzaldehydes



Authors: Maity S.K., Lönnberg T.A.

Publisher: AMER CHEMICAL SOC

Publication year: 2019

Journal: ACS Omega

Journal name in source: ACS OMEGA

Journal acronym: ACS OMEGA

Volume: 4

Issue: 20

First page : 18803

Last page: 18808

Number of pages: 6

ISSN: 2470-1343

eISSN: 2470-1343

DOI: https://doi.org/10.1021/acsomega.9b02804

Self-archived copy’s web address: https://research.utu.fi/converis/portal/detail/Publication/44064800


Abstract
A phthaloyl-protected aminooxymethyl-C-2'-deoxyriboside building block has been prepared and incorporated in the middle of an oligodeoxyribonucleotide. Removal of the phthaloyl protection followed by on-support oximation with either mercurated or palladated benzaldehydes yielded oligonucleotides bearing the respective benzaldoxime metallacycles.

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Last updated on 2024-26-11 at 21:28