Synthesis, characterization, and reactivity toward Nickel(II) of the new saturated 14-Membered P2S2 macrocycles cis-and trans-1,8-diphenyl-1,8-diphospha-4,12-dithiacyclotetradecane
: José Antonio Muñoz, Lluis Escriche, Jaume Casabó, Consuelo Pérez-Jiménez, Raikko Kivekäs, Reijo Sillanpää
Publisher: American Chemical Society
: 2019
: Inorganic Chemistry
: Inorganic Chemistry
: 36
: 5
: 947
: 949
: 4
: 0020-1669
: 1520-510X
DOI: https://doi.org/10.1021/ic960611l
The new saturated 14-membered P2S2 macrocycle 1,8-diphenyl-1,8-diphospha-4,12-dithiacyclotetradecane (14P2S2) has been synthesized and the cis- and trans-isomers have been isolated and characterized. The complexing behavior of these two isomers toward Ni(II) has been tested, and the crystal structure of the [Ni(trans-14P2S2)(CH3CN)](ClO4)2 complex has been solved.
