A1 Refereed original research article in a scientific journal

Emergence of Compartments Formed from Unconventional Surfactants in Dynamic Combinatorial Libraries




AuthorsBoris Bartolec, Giulia Leonetti, Jianwei Li, Wietse Smit, Meniz Altay, Guillermo Monreal Santiago, Yichen Yan, Sijbren Otto

PublisherAmer Chemical Soc

Publication year2019

JournalLangmuir

Journal name in sourceLANGMUIR

Journal acronymLANGMUIR

Volume35

Issue17

First page 5787

Last page5792

Number of pages6

ISSN0743-7463

eISSN1520-5827

DOIhttps://doi.org/10.1021/acs.langmuir.8b03662

Self-archived copy’s web addresshttps://research.utu.fi/converis/portal/detail/Publication/40885253


Abstract
Assembly processes can drive the selection of self-assembling molecules in dynamic combinatorial libraries, yielding self-synthesizing materials. We now show how such selection in a dynamic combinatorial library made from an amphiphilic building block which, by itself, assembles into micelles, can yield membranous aggregates ranging from vesicles to sponge phases. These aggregates are made from a mixture of unconventional surfactant molecules, showing the power of dynamic combinatorial selection approaches for the discovery of new, not readily predictable, self-assembly motifs.

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