A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä

Oxidovanadium(v) complexes with L-proline-based amino acid phenolates




TekijätSalonen P, Peuronen A, Sinkkonen J, Lehtonen A

KustantajaELSEVIER SCIENCE SA

Julkaisuvuosi2019

JournalInorganica Chimica Acta

Tietokannassa oleva lehden nimiINORGANICA CHIMICA ACTA

Lehden akronyymiINORG CHIM ACTA

Vuosikerta489

Aloitussivu108

Lopetussivu114

Sivujen määrä7

ISSN0020-1693

eISSN1873-3255

DOIhttps://doi.org/10.1016/j.ica.2019.02.011

Rinnakkaistallenteen osoitehttps://research.utu.fi/converis/portal/detail/Publication/39815004


Tiivistelmä
L-proline was used to prepare chiral, tridentate amino acid phenol proligands H2L1-4. These proligands react with vanadium precursors VO(acac)(2,) VOSO4 center dot 5H(2)O and VO(OPr)(3) in methanol to form the corresponding oxidoalkoxidovanadium(v) complexes 1-4. The complexes crystallize from methanol, and are octahedrally co-ordinated with a general formula [VO(L1-4)(OMe)(MeOH)]. In solution, however, they adopt several different conformations or isomeric structures depending on the solvent.

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Last updated on 2024-26-11 at 11:24