A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
N center dot center dot center dot I halogen bonding supported stabilization of a discrete pseudo-linear [I-12](2-) polyiodide
Tekijät: Peuronen A, Rinta H, Lahtinen M
Kustantaja: ROYAL SOC CHEMISTRY
Julkaisuvuosi: 2015
Journal: CrystEngComm
Tietokannassa oleva lehden nimi: CRYSTENGCOMM
Lehden akronyymi: CRYSTENGCOMM
Vuosikerta: 17
Numero: 8
Aloitussivu: 1736
Lopetussivu: 1740
Sivujen määrä: 5
ISSN: 1466-8033
DOI: https://doi.org/10.1039/c4ce01866d
Tiivistelmä
Two different dicationic N-donors, based on the DABCO diamine, have been studied as templates for polyiodides. The results present a new strategy for polyiodide stabilization, which involves both N center dot center dot center dot I halogen bonding and cation-anion interactions. This is highlighted by the self-assembly of an unprecedented discrete pseudo-linear dodecaiodide species.
Two different dicationic N-donors, based on the DABCO diamine, have been studied as templates for polyiodides. The results present a new strategy for polyiodide stabilization, which involves both N center dot center dot center dot I halogen bonding and cation-anion interactions. This is highlighted by the self-assembly of an unprecedented discrete pseudo-linear dodecaiodide species.
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