A1 Refereed original research article in a scientific journal
N center dot center dot center dot I halogen bonding supported stabilization of a discrete pseudo-linear [I-12](2-) polyiodide
Authors: Peuronen A, Rinta H, Lahtinen M
Publisher: ROYAL SOC CHEMISTRY
Publication year: 2015
Journal: CrystEngComm
Journal name in source: CRYSTENGCOMM
Journal acronym: CRYSTENGCOMM
Volume: 17
Issue: 8
First page : 1736
Last page: 1740
Number of pages: 5
ISSN: 1466-8033
DOI: https://doi.org/10.1039/c4ce01866d
Abstract
Two different dicationic N-donors, based on the DABCO diamine, have been studied as templates for polyiodides. The results present a new strategy for polyiodide stabilization, which involves both N center dot center dot center dot I halogen bonding and cation-anion interactions. This is highlighted by the self-assembly of an unprecedented discrete pseudo-linear dodecaiodide species.
Two different dicationic N-donors, based on the DABCO diamine, have been studied as templates for polyiodides. The results present a new strategy for polyiodide stabilization, which involves both N center dot center dot center dot I halogen bonding and cation-anion interactions. This is highlighted by the self-assembly of an unprecedented discrete pseudo-linear dodecaiodide species.
UTU Research Portal