A4 Refereed article in a conference publication

Increasing coercivity of ferromagnetic zinc oxide with thermal acetylene treatment




AuthorsJäppinen L., Higuchi T., Huhtinen H., Paturi P., Salonen J.

Conference nameIEEE International Conference on Nanotechnology

Publishing placeCork, Ireland

Publication year2018

Book title 18th International Conference on Nanotechnology (IEEE-NANO)

Journal name in source2018 IEEE 18TH INTERNATIONAL CONFERENCE ON NANOTECHNOLOGY (IEEE-NANO)

Journal acronymIEEE CONF NANOTECH

Number of pages4

ISBN978-1-5386-5336-4

ISSN1944-9399

DOIhttps://doi.org/10.1109/NANO.2018.8626406

Self-archived copy’s web addresshttps://research.utu.fi/converis/portal/detail/Publication/39637257


Abstract
We have used a thermal acetylene treatment on ZnO nanorods in order to investigate the possibility of carbon-doping-induced room temperature ferromagnetism in them. The properties of the rods were investigated using SQUID magnetometry and photoelectron spectroscopy and the findings compared to previously reported results. Ferromagnetism was detected in all investigated samples, but no clear correlation between acetylene and the strength of ferromagnetism was observed. A weakening of the hybridization of Zn 3d and O 2p states as a result of acetylene treatment was detected. The coercivity of acetylene-doped samples was observed to be higher than in annealed samples. The findings support the view that ferromagnetism in ZnO is intrinsic in origin and not caused by carbon doping. However, the treatment can still be used to engineer the magnetic properties of the material, as it can tune its surface properties.

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