A1 Refereed original research article in a scientific journal
Anchoring Cu2O nanoparticles on g-C3N4 nanosheets for enhanced photocatalytic performance
Authors: Ma Jian, Hua Yingjie, Cao Yuanke, Jia Chunman, Li Jianwei
Publisher: Elsevier
Publication year: 2024
Journal: Fuel
Journal name in source: Fuel
Volume: 364
ISSN: 0016-2361
eISSN: 1873-7153
DOI: https://doi.org/10.1016/j.fuel.2024.131139
Web address : https://doi.org/10.1016/j.fuel.2024.131139
Self-archived copy’s web address: https://research.utu.fi/converis/portal/detail/Publication/381276279
Abstract
Photocatalytic H2 evolution technology has sparked intense attention as a potential solution to the energy problem and environmental pollution. Cu2O has emerged as a promising photocatalyst for H2 production due to its narrow bandgap, suitable conduction band (CB) position, and easy synthesis. However, overcoming the disadvantage of photocorrosion, which limits the use of Cu2O in hydrogen production, remains a problem. In this work, g-C3N4 nanosheets were introduced as a support and hole acceptor for Cu2O. Experimental results and density functional theory calculation confirmed the creation of heterojunctions at the interface between Cu2O and g-C3N4 nanosheets, which allows the transfer and separation of photogenerated carriers, resulting in an increased photocatalytic H2 production rate (1796.8 μmol/g/h) and outstanding stability. In addition, the composite photocatalyst exhibits an enhanced tetracycline hydrochloride (TC) degradation activity. A “Z-scheme” photocatalysis mechanism involved in the improvement of the composite photocatalyst’s capacity was clearly illustrated. This study reveals that two-dimensional materials with rich functional groups can modify Cu2O for effective photocorrosion inhibition and enhanced photocatalytic activities.
Photocatalytic H2 evolution technology has sparked intense attention as a potential solution to the energy problem and environmental pollution. Cu2O has emerged as a promising photocatalyst for H2 production due to its narrow bandgap, suitable conduction band (CB) position, and easy synthesis. However, overcoming the disadvantage of photocorrosion, which limits the use of Cu2O in hydrogen production, remains a problem. In this work, g-C3N4 nanosheets were introduced as a support and hole acceptor for Cu2O. Experimental results and density functional theory calculation confirmed the creation of heterojunctions at the interface between Cu2O and g-C3N4 nanosheets, which allows the transfer and separation of photogenerated carriers, resulting in an increased photocatalytic H2 production rate (1796.8 μmol/g/h) and outstanding stability. In addition, the composite photocatalyst exhibits an enhanced tetracycline hydrochloride (TC) degradation activity. A “Z-scheme” photocatalysis mechanism involved in the improvement of the composite photocatalyst’s capacity was clearly illustrated. This study reveals that two-dimensional materials with rich functional groups can modify Cu2O for effective photocorrosion inhibition and enhanced photocatalytic activities.
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