B1 Vertaisarvioimaton kirjoitus tieteellisessä lehdessä
Mechanism of pH-independent cleavage and isomerization of 3 '-ribonucleotide phosphodiesters
Tekijät: Kosonen M, Lonnberg H
Kustantaja: MARCEL DEKKER INC
Julkaisuvuosi: 1999
Lehti:Nucleosides & nucleotides
Tietokannassa oleva lehden nimiNUCLEOSIDES & NUCLEOTIDES
Lehden akronyymi: NUCLEOS NUCLEOT
Vuosikerta: 18
Numero: 4-5
Aloitussivu: 1099
Lopetussivu: 1100
Sivujen määrä: 2
ISSN: 0732-8311
DOI: https://doi.org/10.1080/15257779908041658
Tiivistelmä
The detailed mechanisms of pH-independent cleavage and isomerization reactions of the phosphodiester bond are evaluated by examining kinetics of hydrolytic reactions of selected mono- and dialkyl esters of 3'-uridylic acid. The mechanistic choices are made by comparing LFER's between reaction rates and acidity of the alkyl group of phosphodi- and triesters.
The detailed mechanisms of pH-independent cleavage and isomerization reactions of the phosphodiester bond are evaluated by examining kinetics of hydrolytic reactions of selected mono- and dialkyl esters of 3'-uridylic acid. The mechanistic choices are made by comparing LFER's between reaction rates and acidity of the alkyl group of phosphodi- and triesters.
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