Study on optical recognition and electrochemical sensing of a 1,1 '-ferrocenedicarbonylhydrazine derivative for fluoride



: Li JW, Lin H, Jiang P, Lin HK

Publisher: WILEY-BLACKWELL

: 2008

: Applied Organometallic Chemistry

: APPLIED ORGANOMETALLIC CHEMISTRY

: APPL ORGANOMET CHEM

: 22

: 5

: 258

: 261

: 4

: 0268-2605

DOI: https://doi.org/10.1002/aoc.1387


A new compound, 1,1'-di-(p-nitrophenylhydrazino-beta-carbonyl)-ferrocene (1) was designed as an anion receptor based on its hydrogen bonding interaction with anions. Investigation of UV-vis spectra showed that it was an excellent optical sensors for F-. Furthermore, the nature of interaction between it and F- was investigated by H-1 NMR titration experiments. In addition, the efficiency of the receptor applied as an electrochemical sensor for F- was discussed by cyclic voltammetry (CV). Copyright (C) 2008 John Wiley & Sons, Ltd.

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