A1 Refereed original research article in a scientific journal

Study on optical recognition and electrochemical sensing of a 1,1 '-ferrocenedicarbonylhydrazine derivative for fluoride




AuthorsLi JW, Lin H, Jiang P, Lin HK

PublisherWILEY-BLACKWELL

Publication year2008

JournalApplied Organometallic Chemistry

Journal name in sourceAPPLIED ORGANOMETALLIC CHEMISTRY

Journal acronymAPPL ORGANOMET CHEM

Volume22

Issue5

First page 258

Last page261

Number of pages4

ISSN0268-2605

DOIhttps://doi.org/10.1002/aoc.1387


Abstract
A new compound, 1,1'-di-(p-nitrophenylhydrazino-beta-carbonyl)-ferrocene (1) was designed as an anion receptor based on its hydrogen bonding interaction with anions. Investigation of UV-vis spectra showed that it was an excellent optical sensors for F-. Furthermore, the nature of interaction between it and F- was investigated by H-1 NMR titration experiments. In addition, the efficiency of the receptor applied as an electrochemical sensor for F- was discussed by cyclic voltammetry (CV). Copyright (C) 2008 John Wiley & Sons, Ltd.

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