A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Dioxotungsten(VI) complexes with tetradentate [O,N,N,O] ligands: syntheses, spectral characterisation and catalytic applications
Tekijät: Lehtonen A
Kustantaja: ELSEVIER SCIENCE BV
Julkaisuvuosi: 2005
Lehti: Inorganic Chemistry Communications
Tietokannassa oleva lehden nimi: INORGANIC CHEMISTRY COMMUNICATIONS
Lehden akronyymi: INORG CHEM COMMUN
Vuosikerta: 8
Numero: 20
Aloitussivu: 122
Lopetussivu: 124
Sivujen määrä: 3
ISSN: 1387-7003
DOI: https://doi.org/10.1016/j.inoche.2004.11.021
Tiivistelmä
Two new tungsten(VI) complexes of the type WO2(ONNOR) (ONNOR = tetradentate diaminobis(phenolate) ligand) were prepared by the reaction of trisdiolatetungsten(VI) complex W(eg)(3) (eg = 1,2-ethanediolate) and diaminobis(phenol)s in the presence of water. Studied complexes catalysed ROMP of norbornene when activated by Et2AlCl. They also catalysed oxotransfer reaction between DMSO and benzoin. (C) 2004 Elsevier B.V. All rights reserved.
Two new tungsten(VI) complexes of the type WO2(ONNOR) (ONNOR = tetradentate diaminobis(phenolate) ligand) were prepared by the reaction of trisdiolatetungsten(VI) complex W(eg)(3) (eg = 1,2-ethanediolate) and diaminobis(phenol)s in the presence of water. Studied complexes catalysed ROMP of norbornene when activated by Et2AlCl. They also catalysed oxotransfer reaction between DMSO and benzoin. (C) 2004 Elsevier B.V. All rights reserved.
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