A1 Refereed original research article in a scientific journal
Dioxotungsten(VI) complexes with tetradentate [O,N,N,O] ligands: syntheses, spectral characterisation and catalytic applications
Authors: Lehtonen A
Publisher: ELSEVIER SCIENCE BV
Publication year: 2005
Journal:: Inorganic Chemistry Communications
Journal name in source: INORGANIC CHEMISTRY COMMUNICATIONS
Journal acronym: INORG CHEM COMMUN
Volume: 8
Issue: 20
First page : 122
Last page: 124
Number of pages: 3
ISSN: 1387-7003
DOI: https://doi.org/10.1016/j.inoche.2004.11.021
Abstract
Two new tungsten(VI) complexes of the type WO2(ONNOR) (ONNOR = tetradentate diaminobis(phenolate) ligand) were prepared by the reaction of trisdiolatetungsten(VI) complex W(eg)(3) (eg = 1,2-ethanediolate) and diaminobis(phenol)s in the presence of water. Studied complexes catalysed ROMP of norbornene when activated by Et2AlCl. They also catalysed oxotransfer reaction between DMSO and benzoin. (C) 2004 Elsevier B.V. All rights reserved.
Two new tungsten(VI) complexes of the type WO2(ONNOR) (ONNOR = tetradentate diaminobis(phenolate) ligand) were prepared by the reaction of trisdiolatetungsten(VI) complex W(eg)(3) (eg = 1,2-ethanediolate) and diaminobis(phenol)s in the presence of water. Studied complexes catalysed ROMP of norbornene when activated by Et2AlCl. They also catalysed oxotransfer reaction between DMSO and benzoin. (C) 2004 Elsevier B.V. All rights reserved.
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