A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
New practical tungsten(VI) based catalyst systems for ring opening metathesis polymerisation
Tekijät: Lehtonen A, Sillanpaa R
Kustantaja: ELSEVIER SCIENCE BV
Julkaisuvuosi: 2002
Lehti:: Inorganic Chemistry Communications
Tietokannassa oleva lehden nimi: INORGANIC CHEMISTRY COMMUNICATIONS
Lehden akronyymi: INORG CHEM COMMUN
Vuosikerta: 5
Numero: 4
Aloitussivu: 267
Lopetussivu: 268
Sivujen määrä: 2
ISSN: 1387-7003
DOI: https://doi.org/10.1016/S1387-7003(02)00380-5
Tiivistelmä
Tungsten(VI) complexes of the type trans-[WCl2(diol)(OAr)(2)] were studied as catalyst precursors for ROMP of norbornene and dicyclopentadiene. These compounds form active catalysts when treated by simple Grignard reagents, such as methyl magnesium iodide or neophyl magnesium chloride. Moreover, polymerisations can be run under ambient atmosphere without complicated inert atmosphere techniques. (C) 2002 Elsevier Science B.V. All rights reserved.
Tungsten(VI) complexes of the type trans-[WCl2(diol)(OAr)(2)] were studied as catalyst precursors for ROMP of norbornene and dicyclopentadiene. These compounds form active catalysts when treated by simple Grignard reagents, such as methyl magnesium iodide or neophyl magnesium chloride. Moreover, polymerisations can be run under ambient atmosphere without complicated inert atmosphere techniques. (C) 2002 Elsevier Science B.V. All rights reserved.
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