A1 Refereed original research article in a scientific journal
New practical tungsten(VI) based catalyst systems for ring opening metathesis polymerisation
Authors: Lehtonen A, Sillanpaa R
Publisher: ELSEVIER SCIENCE BV
Publication year: 2002
Journal: Inorganic Chemistry Communications
Journal name in source: INORGANIC CHEMISTRY COMMUNICATIONS
Journal acronym: INORG CHEM COMMUN
Volume: 5
Issue: 4
First page : 267
Last page: 268
Number of pages: 2
ISSN: 1387-7003
DOI: https://doi.org/10.1016/S1387-7003(02)00380-5
Abstract
Tungsten(VI) complexes of the type trans-[WCl2(diol)(OAr)(2)] were studied as catalyst precursors for ROMP of norbornene and dicyclopentadiene. These compounds form active catalysts when treated by simple Grignard reagents, such as methyl magnesium iodide or neophyl magnesium chloride. Moreover, polymerisations can be run under ambient atmosphere without complicated inert atmosphere techniques. (C) 2002 Elsevier Science B.V. All rights reserved.
Tungsten(VI) complexes of the type trans-[WCl2(diol)(OAr)(2)] were studied as catalyst precursors for ROMP of norbornene and dicyclopentadiene. These compounds form active catalysts when treated by simple Grignard reagents, such as methyl magnesium iodide or neophyl magnesium chloride. Moreover, polymerisations can be run under ambient atmosphere without complicated inert atmosphere techniques. (C) 2002 Elsevier Science B.V. All rights reserved.
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