Refereed journal article or data article (A1)

Epimers vs. inverse epimers: the C-1 configuration in alnumycin A1




List of Authors: Tahtinen P, Oja T, Dreiack N, Mantsala P, Niemi J, Metsa-Ketela M, Klika KD

Publisher: ROYAL SOC CHEMISTRY

Publication year: 2012

Journal: RSC Advances

Journal name in source: RSC ADVANCES

Journal acronym: RSC ADV

Number in series: 12

Volume number: 2

Issue number: 12

Number of pages: 3

ISSN: 2046-2069

DOI: http://dx.doi.org/10.1039/c2ra20537h


Abstract
The determination of whether two stereoisomers constitute an epimeric pair or if they differ in their configuration at all stereogenic centers bar one can be deceptive, and even more problematic than just absolute configuration determination per se. The latter stereochemical relationship is hereby defined as a pair of inverse epimers and is exemplified by alnumycin A1 to introduce the concept.


Last updated on 2021-24-06 at 08:11