A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Epimers vs. inverse epimers: the C-1 configuration in alnumycin A1
Tekijät: Tahtinen P, Oja T, Dreiack N, Mantsala P, Niemi J, Metsa-Ketela M, Klika KD
Kustantaja: ROYAL SOC CHEMISTRY
Julkaisuvuosi: 2012
Journal: RSC Advances
Tietokannassa oleva lehden nimi: RSC ADVANCES
Lehden akronyymi: RSC ADV
Numero sarjassa: 12
Vuosikerta: 2
Numero: 12
Aloitussivu: 5098
Lopetussivu: 5100
Sivujen määrä: 3
ISSN: 2046-2069
DOI: https://doi.org/10.1039/c2ra20537h
Tiivistelmä
The determination of whether two stereoisomers constitute an epimeric pair or if they differ in their configuration at all stereogenic centers bar one can be deceptive, and even more problematic than just absolute configuration determination per se. The latter stereochemical relationship is hereby defined as a pair of inverse epimers and is exemplified by alnumycin A1 to introduce the concept.
The determination of whether two stereoisomers constitute an epimeric pair or if they differ in their configuration at all stereogenic centers bar one can be deceptive, and even more problematic than just absolute configuration determination per se. The latter stereochemical relationship is hereby defined as a pair of inverse epimers and is exemplified by alnumycin A1 to introduce the concept.
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