A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Cleavage and isomerisation of UpU promoted by dinuclear metal ion complexes
Tekijät: Linjalahti H, Feng G, Mareque-Rivas JC, Mikkola S, Williams NH
Julkaisuvuosi: 2008
Tietokannassa oleva lehden nimi: CHEMISTRY OF NUCLEIC ACID COMPONENTS
Lehden akronyymi: COLL SYMPOS SERIES
Vuosikerta: 10
Aloitussivu: 404
Lopetussivu: 406
Sivujen määrä: 3
ISBN: 978-80-86241-29-6
Tiivistelmä
Reactions of UpU with dinuclear metal ion complexes have been studied. The complexes did not only efficiently promote the cleavage of the phosphodiester bond but, remarkably, catalysed the isomerisation of the diester. This implies that the reaction involves the formation of a sufficiently long-lived phosphorane intermediate which can pseudorotate.
Reactions of UpU with dinuclear metal ion complexes have been studied. The complexes did not only efficiently promote the cleavage of the phosphodiester bond but, remarkably, catalysed the isomerisation of the diester. This implies that the reaction involves the formation of a sufficiently long-lived phosphorane intermediate which can pseudorotate.
Turun yliopiston Tutkimustietojärjestelmän portaali