A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä

Energy-dependent timescales in the dissociation of diiodothiophene dication




TekijätKukk Edwin, Pihlava Lassi, Kooser Kuno, Stråhlman Christian, Maclot Sylvain, Kivimäki Antti

KustantajaROYAL SOC CHEMISTRY

Julkaisuvuosi2023

JournalPhysical Chemistry Chemical Physics

Tietokannassa oleva lehden nimiPHYSICAL CHEMISTRY CHEMICAL PHYSICS

Lehden akronyymiPHYS CHEM CHEM PHYS

Vuosikerta25

Numero7

Aloitussivu5795

Lopetussivu5807

Sivujen määrä13

ISSN1463-9076

eISSN1463-9084

DOIhttps://doi.org/10.1039/d2cp05309h

Verkko-osoitehttps://doi.org/10.1039/D2CP05309H

Rinnakkaistallenteen osoitehttps://research.utu.fi/converis/portal/detail/Publication/178946725


Tiivistelmä
Photodissociation molecular dynamics of gas-phase 2,5-diiodothiophene molecules was studied in an electron-energy-resolved electron-multi-ion coincidence experiment performed at the FinEstBeAMS beamline of MAX IV synchrotron. Following the photoionization of the iodine 4d subshell and the Auger decay, the dissociation landscape of the molecular dication was investigated as a function of the Auger electron energy. Concentrating on an major dissociation pathway, C4H2I2S2+ -> C4H2S+ + I+ + I, and accessing the timescales of the process via ion momentum correlation analysis, it was revealed how this three-body process changes depending on the available internal energy. Using a generalized secondary dissociation model, the process was shown to evolve from secondary dissociation regime towards concerted dissociation as the available energy increased, with the secondary dissociation time constant changing from 1.5 ps to 129 fs. The experimental results were compared with simulations using a stochastic charge-hopping molecular mechanics model. It represented the observed trend and also gave a fair quantitative agreement with the experiment.

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