A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Structural properties and applications of multidentate [O,N,O,X '] aminobisphenolate metal complexes
Tekijät: Wichmann O, Sillanpaa R, Lehtonen A
Kustantaja: ELSEVIER SCIENCE SA
Julkaisuvuosi: 2012
Journal: Coordination Chemistry Reviews
Tietokannassa oleva lehden nimi: COORDINATION CHEMISTRY REVIEWS
Lehden akronyymi: COORDIN CHEM REV
Numero sarjassa: 3-4
Vuosikerta: 256
Numero: 3-4
Aloitussivu: 371
Lopetussivu: 392
Sivujen määrä: 22
ISSN: 0010-8545
DOI: https://doi.org/10.1016/j.ccr.2011.09.007
Tiivistelmä
The coordination geometry of the metal centre can be controlled by the ligand design. Especially, the ortho-substituents of the phenolate moieties as well as the nature of side-arm donor influence the structure and reactivity of the complexes formed. Depending on the metal ion and the ligand environment, the complexes formed can be monomeric or dimeric ones. Several heterobimetallic complexes are also known. (c) 2011 Elsevier B.V. All rights reserved.
The coordination geometry of the metal centre can be controlled by the ligand design. Especially, the ortho-substituents of the phenolate moieties as well as the nature of side-arm donor influence the structure and reactivity of the complexes formed. Depending on the metal ion and the ligand environment, the complexes formed can be monomeric or dimeric ones. Several heterobimetallic complexes are also known. (c) 2011 Elsevier B.V. All rights reserved.
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