A1 Refereed original research article in a scientific journal
Structural properties and applications of multidentate [O,N,O,X '] aminobisphenolate metal complexes
Authors: Wichmann O, Sillanpaa R, Lehtonen A
Publisher: ELSEVIER SCIENCE SA
Publication year: 2012
Journal: Coordination Chemistry Reviews
Journal name in source: COORDINATION CHEMISTRY REVIEWS
Journal acronym: COORDIN CHEM REV
Number in series: 3-4
Volume: 256
Issue: 3-4
First page : 371
Last page: 392
Number of pages: 22
ISSN: 0010-8545
DOI: https://doi.org/10.1016/j.ccr.2011.09.007
Abstract
The coordination geometry of the metal centre can be controlled by the ligand design. Especially, the ortho-substituents of the phenolate moieties as well as the nature of side-arm donor influence the structure and reactivity of the complexes formed. Depending on the metal ion and the ligand environment, the complexes formed can be monomeric or dimeric ones. Several heterobimetallic complexes are also known. (c) 2011 Elsevier B.V. All rights reserved.
The coordination geometry of the metal centre can be controlled by the ligand design. Especially, the ortho-substituents of the phenolate moieties as well as the nature of side-arm donor influence the structure and reactivity of the complexes formed. Depending on the metal ion and the ligand environment, the complexes formed can be monomeric or dimeric ones. Several heterobimetallic complexes are also known. (c) 2011 Elsevier B.V. All rights reserved.
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