A1 Journal article – refereed
Oxidovanadium(v) complexes with L-proline-based amino acid phenolates




List of Authors: Salonen P, Peuronen A, Sinkkonen J, Lehtonen A
Publisher: ELSEVIER SCIENCE SA
Publication year: 2019
Journal: Inorganica Chimica Acta
Journal name in source: INORGANICA CHIMICA ACTA
Journal acronym: INORG CHIM ACTA
Volume number: 489
Number of pages: 7
ISSN: 0020-1693
eISSN: 1873-3255

Abstract
L-proline was used to prepare chiral, tridentate amino acid phenol proligands H2L1-4. These proligands react with vanadium precursors VO(acac)(2,) VOSO4 center dot 5H(2)O and VO(OPr)(3) in methanol to form the corresponding oxidoalkoxidovanadium(v) complexes 1-4. The complexes crystallize from methanol, and are octahedrally co-ordinated with a general formula [VO(L1-4)(OMe)(MeOH)]. In solution, however, they adopt several different conformations or isomeric structures depending on the solvent.

Last updated on 2019-09-04 at 14:18