A1 Refereed original research article in a scientific journal

Acid sites modulation of siliceous-based mesoporous material by post synthesis methods




AuthorsPizzolitto Cristina, Ghedini Elena, Taghavi Somayeh, Menegazzo Federica, Cruciani Giuseppe, Peurla Markus, Eränen Kari, Heinmaa Ivo, Aho Atte, Kumar Narendra, Murzin Dmitry Yu, Salmi Tapio, Signoretto Michela

PublisherELSEVIER

Publication year2021

JournalMicroporous and Mesoporous Materials

Journal name in sourceMICROPOROUS AND MESOPOROUS MATERIALS

Journal acronymMICROPOR MESOPOR MAT

Article numberARTN 111459

Volume328

Number of pages11

ISSN1387-1811

eISSN1873-3093

DOIhttps://doi.org/10.1016/j.micromeso.2021.111459


Abstract

The present work is focused on the improvement of an effective approach to tailor the acidity of silica alumina composite. SBA-15 was selected based on high surface area, uniform porosity and large mesopores. Modification of SBA-15 was performed to improve both Lewis and Bronsted acidities and hence catalyst activity. Therefore, introduction of alumina as a co-catalyst was carried out to enhance Lewis acid sites through its incorporation into the silica network. Evaporation impregnation method was evaluated for incorporation of aluminium to SBA-15 and materials with different SiO2/Al2O3 ratios were prepared. Acidity and morphological features of the materials were assessed using XRD, EDX, SEM, TEM, N2-physisorption, 27Al MAS-NMR and FTIR with pyridine. Bronsted acidity was attained by the introduction of sulfonic acid groups in the final catalyst via the postsynthesis grafting method. Therefore, the balanced Lewis and Br phi nsted acidities and proper porosity of modified SBA-15 led to its efficient performance in the conversion of glucose as a biomass-based model component to levulinic acid.



Last updated on 2024-26-11 at 21:17