A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä

Calixarenes functionalized with phosphine oxide and diamide functions as extractants and ionofores for rare-earth metals




TekijätAlyapyshev MY, Babain VA, Boyko VI, Eliseev II, Kirsanov DO, Klimchuk OV, Legin AV, Mikhailina ES, Rodik RV, Smirnov IV

KustantajaSPRINGER

Julkaisuvuosi2010

JournalJournal of Inclusion Phenomena and Macrocyclic Chemistry

Tietokannassa oleva lehden nimiJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY

Lehden akronyymiJ INCL PHENOM MACRO

Vuosikerta67

Numero1-2

Aloitussivu117

Lopetussivu126

Sivujen määrä10

ISSN1388-3127

DOIhttps://doi.org/10.1007/s10847-009-9685-8

Verkko-osoitehttps://link.springer.com/article/10.1007/s10847-009-9685-8


Tiivistelmä
Calixarene-based ligands with phosphine oxide and diamide functions at wide and narrow rims are synthesized and studied as extracting agents for liquid extraction and ionophores for polymeric electrochemical ion sensors. Calixarene ligands are compared with corresponding phosphine oxide and diamide ligands which are not attached to the calixarene platform. Extraction and sensor properties of the ligands were studied in different metal ion solution with special attention paid to rare-earth metals. Attachment of phosphine oxide groups to the calixarene platform leads to the sharp increase of both extraction and sensing ability of the corresponding systems comparing to non-bonded phosphine oxide. In case of the diamide derivatives attached to the calixarene performance of corresponding ligands was similar to those of non-bonded diamides.



Last updated on 2024-26-11 at 19:30