Rural areas around the world are increasingly dealing with energy and environmental challenges. These challenges are particularly acute in developing countries, where persistent reliance on traditional energy sources—such as wood fuel—intersects with concerns about forest conservation and energy sustainability. While wood fuel use is often portrayed as unsustainable, it is important to acknowledge that much of it remains ecologically viable and socially embedded. This study explores the role of rural entrepreneurs in shaping low-carbon transitions at the intersection of household energy practices and environmental stewardship. Fieldwork was carried out in four rural Zambian communities in 2016 and complemented by 2024 follow-up reports. It examines the connections between household energy choices, greenhouse gas emissions, and forest resource dynamics. Findings reveal that over 60% of rural households rely on charcoal for cooking, with associated emissions estimated between 80 and 150 kg CO₂ per household per month. Although this is significantly lower than the average per capita carbon footprint in industrialized countries, such emissions are primarily biogenic in nature. While rural communities contribute minimally to global climate change, their practices have significant local environmental consequences. This study draws attention to the structural constraints as well as emerging opportunities within Zambia’s rural energy economy. It positions rural entrepreneurs not merely as policy recipients but as active agents of innovation, environmental monitoring, and participatory resource governance. A model is proposed to support sustainable rural energy transitions by aligning forest management with context-sensitive emissions strategies.