A1 Refereed original research article in a scientific journal
Operando high-temperature near-ambient pressure X-ray photoelectron spectroscopy and impedance spectroscopy study of Ni - Ce0.9Gd0.1O2-δ solid oxide fuel cell anode
Authors: Kooser K, Kaambre T, Vestli M, Joost U, Urpelainen S, Kook M, Bournel F, Gallet JJ, Lust E, Kukk E, Nurk G
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Publication year: 2020
Journal: International Journal of Hydrogen Energy
Journal name in source: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Journal acronym: INT J HYDROGEN ENERG
Volume: 45
Issue: 46
First page : 25286
Last page: 25298
Number of pages: 13
ISSN: 0360-3199
DOI: https://doi.org/10.1016/j.ijhydene.2020.06.228
Abstract
In this study we present the results of operando high temperature near-ambient-pressure xray photoelectron spectroscopy (HT-NAP-XPS) measurements of a pulsed laser deposited thin film Ni - Ce0.9Gd0.1O2-δ model electrode. In our measurements, we have used the novel three electrode dual-chamber electrochemical cell developed in our previous work at different H2 pressures and at different electrochemical conditions at around 650 °C. The possible redox reactions on the anode surface (Ni2+ <-> Ni0; Ce4+ <-> Ce3+) were investigated by HT-NAP-XPS technique simultaneously with electrochemical impedance spectroscopy measurements. The oxygen partial pressure in counter and reference electrode compartment was controlled at 0.2 bar. Changes in electronic structure of the Ce 3d and Ni 2p photoelectron spectra caused by electrode potential and H2 pressure variations were observed and estimated by curve fitting procedure. The O 1s and valence band photoelectron signals were used for depth probing of the chemical composition and redox changes at Ni-GDC and for studying the influence of the electrochemical polarization on the chemical state of Ni-GDC surface atoms.As a result changes in oxidation state of electrode surface atoms caused by electrode polarization and oxide ion flux through the membrane were detected with simultaneous significant variation of electrochemical impedance. (c) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
In this study we present the results of operando high temperature near-ambient-pressure xray photoelectron spectroscopy (HT-NAP-XPS) measurements of a pulsed laser deposited thin film Ni - Ce0.9Gd0.1O2-δ model electrode. In our measurements, we have used the novel three electrode dual-chamber electrochemical cell developed in our previous work at different H2 pressures and at different electrochemical conditions at around 650 °C. The possible redox reactions on the anode surface (Ni2+ <-> Ni0; Ce4+ <-> Ce3+) were investigated by HT-NAP-XPS technique simultaneously with electrochemical impedance spectroscopy measurements. The oxygen partial pressure in counter and reference electrode compartment was controlled at 0.2 bar. Changes in electronic structure of the Ce 3d and Ni 2p photoelectron spectra caused by electrode potential and H2 pressure variations were observed and estimated by curve fitting procedure. The O 1s and valence band photoelectron signals were used for depth probing of the chemical composition and redox changes at Ni-GDC and for studying the influence of the electrochemical polarization on the chemical state of Ni-GDC surface atoms.As a result changes in oxidation state of electrode surface atoms caused by electrode polarization and oxide ion flux through the membrane were detected with simultaneous significant variation of electrochemical impedance. (c) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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