Sterically controlled self-assembly of tetrahedral M6L4 cages via cationic N-donor ligands



: Peuronen A, Forsblom S, Lahtinen M

Publisher: ROYAL SOC CHEMISTRY

: 2014

: Chemical Communications

: CHEMICAL COMMUNICATIONS

: CHEM COMMUN

: 50

: 41

: 5469

: 5472

: 4

: 1359-7345

DOI: https://doi.org/10.1039/c3cc49663e


Tripodal cationic N-donor ligands exhibit sterically controlled self-assembly of tetrahedral M6L4 coordination cages that promote selective anion encapsulation (PF6- > OTf (-)) in the solid state. The described method is a potential template for stepwise assembly of hetero-ligand coordination cages and polymers.



Last updated on 2024-26-11 at 15:09