A1 Refereed original research article in a scientific journal
Poly[[mu-N,N'-bis(2-hydroxyethyl)-N,N,N',N'-tetramethylpropane-1,3-diaminium-kappa O-2:O']tetra-mu-bromido-dibromidodimanganese(II)]
Authors: Rinta H, Peuronen A, Lahtinen M
Publisher: INT UNION CRYSTALLOGRAPHY
Publication year: 2012
Journal: Acta Crystallographica Section E: Crystallographic Communications
Journal name in source: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Journal acronym: ACTA CRYSTALLOGR E
Volume: 68
First page : M1453
Last page: +
Number of pages: 10
ISSN: 2056-9890
DOI: https://doi.org/10.1107/S1600536812044765
Abstract
The asymmetric unit of the title three-dimensional coordination polymer, [Mn2Br6(C11H28N2O2)](n), consists of one Mn-II cation, half of a dicationic N, N'-bis(2-hydroxyethyl)N, N,N',N'-tetramethylpropane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation axis), and three bromide ions. The Mn-II cation is coordinated by a single L ligand via the hydroxy O atom and by five bromide ions, resulting in a distorted octahedral MnBr5O coordination geometry. Four of the bromide ions are bridging to two adjacent Mn-II atoms, thereby forming polymeric chains along the a and b axes. The L units act as links between neighbouring Mn-(mu-Br)(2)-Mn chains, also forming a polymeric continuum along the c axis, which completes the formation of a three-dimensional network. Classical O-H center dot center dot center dot Br hydrogen bonds are present. The distance between adjacent Mn-II atoms is 4.022 (1) angstrom.
The asymmetric unit of the title three-dimensional coordination polymer, [Mn2Br6(C11H28N2O2)](n), consists of one Mn-II cation, half of a dicationic N, N'-bis(2-hydroxyethyl)N, N,N',N'-tetramethylpropane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation axis), and three bromide ions. The Mn-II cation is coordinated by a single L ligand via the hydroxy O atom and by five bromide ions, resulting in a distorted octahedral MnBr5O coordination geometry. Four of the bromide ions are bridging to two adjacent Mn-II atoms, thereby forming polymeric chains along the a and b axes. The L units act as links between neighbouring Mn-(mu-Br)(2)-Mn chains, also forming a polymeric continuum along the c axis, which completes the formation of a three-dimensional network. Classical O-H center dot center dot center dot Br hydrogen bonds are present. The distance between adjacent Mn-II atoms is 4.022 (1) angstrom.
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