A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Cobalt(III) complex with a redox non-innocent bis (o-aminophenol)
Tekijät: Lehtonen Ari, Sapkota Narhari, Peuronen Anssi
Kustantaja: ELSEVIER
Kustannuspaikka: AMSTERDAM
Julkaisuvuosi: 2024
Journal: Inorganic Chemistry Communications
Tietokannassa oleva lehden nimi: INORGANIC CHEMISTRY COMMUNICATIONS
Lehden akronyymi: INORG CHEM COMMUN
Artikkelin numero: 111704
Vuosikerta: 159
Sivujen määrä: 4
ISSN: 1387-7003
eISSN: 1879-0259
DOI: https://doi.org/10.1016/j.inoche.2023.111704
Verkko-osoite: https://www.sciencedirect.com/science/article/pii/S1387700323013163?via%3Dihub
Rinnakkaistallenteen osoite: https://research.utu.fi/converis/portal/detail/Publication/387182743
The redox non-innocent ligand bis(o-aminophenol) N,N '-bis(3,5-di-tertbutyl-2-hydroxy-phenyl)-1,2-phenyl-enediamine, H4L, reacts with CoCl2.6H2O in a methanol solution under aerobic conditions to form [Co(HL)2]. Both bis(o-aminophenol) ligands coordinate as tridentate and the ligand set can be described as a resonance structure of two partially oxidized ligands, while the formal oxidation state of the metal centre appears as + III. In this resonance structure, one ligand carries an odd electron, which makes the Co(III) complex paramagnetic.
Ladattava julkaisu This is an electronic reprint of the original article. |  |
