A1 Journal article – refereed

Enhanced electron transfer in composite films of reduced graphene oxide and poly(N-methylaniline)




List of Authors: Lindfors T, Österholm A, Kauppila J, Gyurcsányi RE

Publication year: 2013

Journal: Carbon

Journal name in source: Carbon

Number in series: 0

Volume number: 63

Issue number: 0

Number of pages: 5

ISSN: 0008-6223

DOI: http://dx.doi.org/10.1016/j.carbon.2013.07.022

URL: http://www.sciencedirect.com/science/article/pii/S0008622313006441


Abstract
Abstract Poly(N-methylaniline) (PNMA) has been electropolymerized for the first time from a graphene oxide (GO) dispersion containing 1.0 M HClO4. Both \{GO\} and perchlorate were incorporated in the \{PNMA\} matrix during the electropolymerization resulting in the formation of a mixed composite material of PNMA-ClO4 and PNMA-GO. Under the acidic polymerization conditions, the carboxylic groups of \{GO\} are undissociated and \{GO\} is therefore mostly mechanically entrapped in the \{PNMA\} matrix while perchlorate functions as the primary charge compensating ion. Electrochemical reduction at −0.85 V improved the electron transfer of the composite film due to reduction of \{GO\} in the \{PNMA\} matrix.


Research Areas


Last updated on 2021-24-06 at 09:05