A1 Refereed original research article in a scientific journal
Procyanidin xylosides from the bark of Betula pendula
Authors: Liimatainen J, Karonen M, Sinkkonen J
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Publication year: 2012
Journal: Phytochemistry
Journal name in source: PHYTOCHEMISTRY
Journal acronym: PHYTOCHEMISTRY
Volume: 76
First page : 178
Last page: 183
Number of pages: 6
ISSN: 0031-9422
DOI: https://doi.org/10.1016/j.phytochem.2012.01.008
Abstract
A procyanidin dimer xyloside, catechin-(4 alpha -> 8)-7-O-beta-xylopyranosyl-catechin, was isolated from the inner bark of Betula pendula and its structure was determined using ID and 2D NMR, CD and high-resolution ESIMS. Interestingly, the 7-O-beta-xylopyranose unit was found to be present in the lower terminal unit of the dimer. In addition to this procyanidin dimer xyloside, an entire series of oligomeric and polymeric procyanidin xylosides was detected. Their structures were investigated by hydrophilic interaction HPLC-HRESIMS. Procyanidin glycosides are still rarely found in nature. (C) 2012 Elsevier Ltd. All rights reserved.
A procyanidin dimer xyloside, catechin-(4 alpha -> 8)-7-O-beta-xylopyranosyl-catechin, was isolated from the inner bark of Betula pendula and its structure was determined using ID and 2D NMR, CD and high-resolution ESIMS. Interestingly, the 7-O-beta-xylopyranose unit was found to be present in the lower terminal unit of the dimer. In addition to this procyanidin dimer xyloside, an entire series of oligomeric and polymeric procyanidin xylosides was detected. Their structures were investigated by hydrophilic interaction HPLC-HRESIMS. Procyanidin glycosides are still rarely found in nature. (C) 2012 Elsevier Ltd. All rights reserved.
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