A1 Refereed original research article in a scientific journal
Dioxomolybdenum(VI) complexes of chelating alkoxides
Authors: Lehtonen A, Sillanpaa R
Publisher: MUNKSGAARD INT PUBL LTD
Publication year: 1999
Journal:Acta Chemica Scandinavica
Journal name in sourceACTA CHEMICA SCANDINAVICA
Journal acronym: ACTA CHEM SCAND
Volume: 53
Issue: 12
First page : 1078
Last page: 1082
Number of pages: 5
ISSN: 0904-213X
DOI: https://doi.org/10.3891/acta.chem.scand.53-1078
Abstract
Molybdenum trioxides MoO3 or MoO3. 2H(2)O reacted with alcohol ethers (HOROR') to form complexes having the general formula [MoO2(OROR')(2)] where HOROR' = 2-methoxyethanol (Hmet) or tetrahydropyran-2-methanol (Hpyr). In these compounds the Mo-VI has a distorted octahedral coordination geometry. The reaction of [MoO2(pyr)(2)] with ditertiary diol 1,1'-bicyclohexane-1,1'diol (H(2)bicy) in acetonitrile solution produced the complex [MoO2(Hbicy)(pyr)] and in the presence of methanol the product was the dimeric complex [{MoO2(Hbicy) (OMe)}(2)]. 2MeOH. The structures of four complexes were confirmed by X-ray diffraction.
Molybdenum trioxides MoO3 or MoO3. 2H(2)O reacted with alcohol ethers (HOROR') to form complexes having the general formula [MoO2(OROR')(2)] where HOROR' = 2-methoxyethanol (Hmet) or tetrahydropyran-2-methanol (Hpyr). In these compounds the Mo-VI has a distorted octahedral coordination geometry. The reaction of [MoO2(pyr)(2)] with ditertiary diol 1,1'-bicyclohexane-1,1'diol (H(2)bicy) in acetonitrile solution produced the complex [MoO2(Hbicy)(pyr)] and in the presence of methanol the product was the dimeric complex [{MoO2(Hbicy) (OMe)}(2)]. 2MeOH. The structures of four complexes were confirmed by X-ray diffraction.
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