A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Tungsten(VI) p-tert-butylcalix[4]arene diolato complexes. Crystal structure and reactions of [W(t-butylcalix)(eg)]
Tekijät: Lehtonen A, Sillanpaa R
Kustantaja: PERGAMON-ELSEVIER SCIENCE LTD
Julkaisuvuosi: 1998
Lehti:: Polyhedron
Tietokannassa oleva lehden nimi: POLYHEDRON
Lehden akronyymi: POLYHEDRON
Vuosikerta: 17
Numero: 19
Aloitussivu: 3327
Lopetussivu: 3330
Sivujen määrä: 4
ISSN: 0277-5387
DOI: https://doi.org/10.1016/S0277-5387(98)00112-0
Tiivistelmä
Air- and moisture stable tungsten(VI) calixarene complex was prepared from [W(eg)(3)] (H(2)eg = 1,2-ethanediol) and H(4)tbcalix (p-tert-butylcalix[4] arene) by a ligand exchange reaction. X-ray structure of [W(tbcalix)(eg)] reveals that tungsten ion is octahedrally surrounded by six oxygen atoms. The reaction of the obtained complex with thionyl chloride or water leads to known dichloro and oxo complexes. (C) 1998 Elsevier Science Ltd. All rights reserved.
Air- and moisture stable tungsten(VI) calixarene complex was prepared from [W(eg)(3)] (H(2)eg = 1,2-ethanediol) and H(4)tbcalix (p-tert-butylcalix[4] arene) by a ligand exchange reaction. X-ray structure of [W(tbcalix)(eg)] reveals that tungsten ion is octahedrally surrounded by six oxygen atoms. The reaction of the obtained complex with thionyl chloride or water leads to known dichloro and oxo complexes. (C) 1998 Elsevier Science Ltd. All rights reserved.
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