A1 Refereed original research article in a scientific journal
Spectroelectrochemical characterization of thin fullerene films in room temperature ionic liquids
Authors: Damlin P, Kvarnstrom C, Ivaska A
Publisher: ELSEVIER SCIENCE SA
Publication year: 2006
Journal:: Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
Journal name in source: JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Journal acronym: J ELECTROANAL CHEM
Volume: 590
Issue: 2
First page : 190
Last page: 197
Number of pages: 8
ISSN: 0022-0728
DOI: https://doi.org/10.1016/j.jelechem.2006.03.009
Abstract
Room-temperature ionic liquids were used as electrolytes for in situ studies of the transitions of solution cast fullerene films. 1-Butyl-3-methyl-imidazolium tetrafluoroborate (BMIMBF4), 1-butyl-3-methyl-imidazolium hexafluorophosphate (BMIMPF6) and 1-butyl-2,3dimethylimidazolium tetrafluoroborate (BDiMIMBF(4)) were used in this study and the techniques used are cyclic voltammetry and in situ attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy. Infrared spectra were recorded during the reversible redox processes of the C-60 films showing a three-step one electron reduction and reoxidation reaction. After reoxidation some part of the C-60 film remained in its C-60 form. The IR bands obtained during electrochemical reduction of C-60 in ionic liquids were compared with the spectra reported for C-60 films upon reduction in the presence of different cations in organic solutions. (c) 2006 Elsevier B.V. All rights reserved.
Room-temperature ionic liquids were used as electrolytes for in situ studies of the transitions of solution cast fullerene films. 1-Butyl-3-methyl-imidazolium tetrafluoroborate (BMIMBF4), 1-butyl-3-methyl-imidazolium hexafluorophosphate (BMIMPF6) and 1-butyl-2,3dimethylimidazolium tetrafluoroborate (BDiMIMBF(4)) were used in this study and the techniques used are cyclic voltammetry and in situ attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy. Infrared spectra were recorded during the reversible redox processes of the C-60 films showing a three-step one electron reduction and reoxidation reaction. After reoxidation some part of the C-60 film remained in its C-60 form. The IR bands obtained during electrochemical reduction of C-60 in ionic liquids were compared with the spectra reported for C-60 films upon reduction in the presence of different cations in organic solutions. (c) 2006 Elsevier B.V. All rights reserved.
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